Vapor Pressure

  • It is the pressure exerted by the vapor when a liquid or solid is in equilibrium with its vapour phase.
  • It’s a measure of a substance’s tendency to evaporate.

Factors Affecting:

  • Temperature:

    • Higher temperature increases vapour pressure because more particles have enough energy to escape into the vapour phase.
  • Nature of the Liquid:

    • Substances with weaker intermolecular forces have higher vapour pressure.
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Dynamic Equilibrium:

  • In a closed container, when the rate of evaporation equals the rate of condensation, the vapour pressure stabilizes.
  • Example: A closed bottle of water eventually reaches a state where the water vapour in the air above the liquid exerts a constant pressure.

Importance of Vapor Pressure:

  1. Weather and Climate: Influences humidity and the formation of clouds.
  2. Industrial Applications: Important in processes like distillation and refrigeration.
  3. Safety: High vapour pressure substances can be more flammable or pose evaporation-related hazards.
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Example of Vapor Pressure:

  • At 25°C, water has a vapour pressure of about 23.8 mmHg. If placed in a sealed container, water vapour will exert this pressure when equilibrium is reached.

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