- It is the pressure exerted by the vapor when a liquid or solid is in equilibrium with its vapour phase.
- It’s a measure of a substance’s tendency to evaporate.
Factors Affecting:
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Temperature:
- Higher temperature increases vapour pressure because more particles have enough energy to escape into the vapour phase.
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Nature of the Liquid:
- Substances with weaker intermolecular forces have higher vapour pressure.
Dynamic Equilibrium:
- In a closed container, when the rate of evaporation equals the rate of condensation, the vapour pressure stabilizes.
- Example: A closed bottle of water eventually reaches a state where the water vapour in the air above the liquid exerts a constant pressure.
Importance of Vapor Pressure:
- Weather and Climate: Influences humidity and the formation of clouds.
- Industrial Applications: Important in processes like distillation and refrigeration.
- Safety: High vapour pressure substances can be more flammable or pose evaporation-related hazards.
Example of Vapor Pressure:
- At 25°C, water has a vapour pressure of about 23.8 mmHg. If placed in a sealed container, water vapour will exert this pressure when equilibrium is reached.
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