Introduction: Acids, Bases, and Buffer

Acids, bases and buffers are essential concepts in chemistry and play critical roles in various biological and industrial processes.

Acids:

  • Acids are substances that donate hydrogen ions (H⁺) or protons when dissolved in water.
  • They typically have a sour taste and can be corrosive to metals.
  • Acids can be classified into two main categories:
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Strong Acids:

  • These acids ionize completely in water, releasing all their hydrogen ions.
  • Examples include hydrochloric acid (HCl), sulfuric acid (H₂SO₄), and nitric acid (HNO₃).

Weak Acids:

  • These acids ionize only partially in water, releasing only a small fraction of their hydrogen ions.
  • Examples include acetic acid (CH₃COOH), carbonic acid (H₂CO₃), and phosphoric acid (H₃PO₄).
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Bases:

  • Bases are substances that accept hydrogen ions (H⁺) or donate hydroxide ions (OH⁻) when dissolved in water.
  • They typically have a bitter taste, feel slippery, and can be corrosive to organic materials.
  • Bases can also be classified into two main categories:

Strong Bases:

  • These bases ionize completely in water, releasing all their hydroxide ions.
  • Examples include sodium hydroxide (NaOH), potassium hydroxide (KOH), and calcium hydroxide (Ca(OH)₂).
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Weak Bases:

  • These bases ionize only partially in water, releasing only a small fraction of their hydroxide ions.
  • Examples include ammonia (NH₃), methylamine (CH₃NH₂), and pyridine (C₅H₅N).

Buffers:

  • Buffers are solutions that resist significant changes in pH when small amounts of acid or base are added.
  • They usually consist of a weak acid and its conjugate base, or a weak base and its conjugate acid.
  • Buffers are essential for maintaining a stable pH in biological systems, industrial processes, and analytical chemistry.

For example, in biological contexts, the bicarbonate buffer system helps maintain a stable pH in blood:

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  • The buffer consists of carbonic acid (H₂CO₃, a weak acid) and bicarbonate ions (HCO₃⁻, its conjugate base).
  • When an acid is added, the bicarbonate ions react with the hydrogen ions to form carbonic acid, neutralizing the added acid and minimizing the pH change.
  • Conversely, when a base is added, carbonic acid donates hydrogen ions, which react with hydroxide ions to form water, neutralizing the added base and again minimizing the pH change.

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