Classification of Dispersed Systems & Their General Characteristics

  • Classification of Dispersed Systems & Their General Characteristics divides systems by particle size and phase.
  • Classification of Dispersed Systems & Their General Characteristics explains stability, interactions, and properties.

Definition:

  • Dispersed systems consist of two phases:
  • Dispersed phase (internal phase): The substance that is dispersed.
  • Dispersion medium (continuous phase): The substance in which the dispersed phase is distributed.
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Classification of Dispersed Systems:

  • Dispersed systems are classified based on:
  • Particle size of the dispersed phase
  • Physical state of both the dispersed phase and dispersion medium

1. Based on Particle Size

Type Particle Size Range Example
Molecular (True) Solutions < 1 nm NaCl in water
Colloidal Dispersions 1 – 1000 nm (1 nm to 1 µm) Milk, gels, magmas
Coarse Dispersions > 1 µm Suspensions, emulsions

2. Based on Physical States (Phases)

There are 8 types depending on the physical state of dispersed phase and dispersion medium.

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Dispersed Phase Dispersion Medium Type Example
Solid Gas Solid aerosol Smoke, airborne particles
Liquid Gas Liquid aerosol Mist, fog, sprays
Gas Liquid Foam Shaving cream, whipped cream
Solid Liquid Sol Paints, gold sol
Liquid Liquid Emulsion Milk, creams
Gas Solid Solid foam Pumice, foam rubber
Liquid Solid Gel Gelatin, jelly
Solid Solid Solid sol Colored glass, pearls

General Characteristics of Dispersed Systems:

  • Heterogeneous nature: Composed of two distinct phases.
  • Stability: Varies from very stable (true solutions) to unstable (coarse dispersions).
  • Visibility: Particles in colloidal systems are not visible to the naked eye but can be detected under an ultramicroscope.
  • Filterability: Colloidal particles can pass through ordinary filters but not through ultrafilters.
  • Brownian motion: Colloidal particles exhibit random movement due to collisions with dispersion medium molecules.
  • Tyndall effect: Scattering of light by colloidal particles, making the path of light visible.

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