Sodium Bicarbonate (NaHCO₃)

Properties of Sodium Bicarbonate:

  • White crystalline powder
  • Odorless
  • Soluble in water
  • Slightly alkaline taste
  • Decomposes at high temperatures
  • Chemical formula: NaHCO₃

Preparation (Solvay Process):

  • Prepared industrially by-passing carbon dioxide and ammonia through a concentrated sodium chloride (brine) solution.
  • Sodium bicarbonate precipitates out and is then filtered, washed, and dried.
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Uses of Sodium Bicarbonate:

  • As a systemic antacid to treat acid indigestion, heartburn, and upset stomach.
  • As a leavening agent in baking.
  • As an odor neutralizer and cleaning agent.
  • In the management of metabolic acidosis and certain drug overdoses (under medical supervision).

Assay (Acid-Base Titration):

  1. Prepare a Standard Solution: Dissolve a known amount of a strong acid, such as hydrochloric acid (HCl), in water to create a solution with a known concentration.
  2. Sample Preparation: Weigh an accurate amount of NaHCO₃ and dissolve it in water.
  3. Add Indicator: Add a pH indicator, such as phenolphthalein, to the NaHCO₃ solution. The indicator changes color at neutralization.
  4. Titrate: Slowly add the standard HCl solution to the NaHCO₃ solution while stirring. NaHCO₃ reacts with HCl, forming water, carbon dioxide (CO₂), and sodium chloride (NaCl). The endpoint is reached when the indicator changes color.
  5. Calculate Concentration: Measure the volume of HCl used in the titration to calculate the concentration or purity of NaHCO₃.
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