Definition of Spreading Coefficient
- The spreading coefficient (S) indicates the ability of one liquid to spread over another. It is defined as:
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$S = \gamma_S – (\gamma_L + \gamma_{SL})$
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- where:
- γS is the surface tension of the sublayer liquid.
- γL is the surface tension of the spreading liquid.
- γSL is the interfacial tension between the two liquids.
Interpretation of Spreading Coefficient
- Positive SSS: Spreading occurs spontaneously.
- Negative SSS: No spontaneous spreading.
Applications
- Topical Formulations: Influences the spreadability of creams and ointments.
- Coating Processes: Affects film formation on solid surfaces.
- Emulsion Stability: Determines the ease of emulsification.
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