Units of Basic Rate Constants

The units of k depend on the reaction order. To ensure the rate has units of concentration/time (e.g., mol/L·s), units of k vary:

Reaction Order Rate Expression Units of k
Zero Rate = k mol·L⁻¹·s⁻¹ or concentration/time
First Rate = s⁻¹ or time⁻¹
Second Rate = L·mol⁻¹·s⁻¹ or concentration⁻¹·time⁻¹v

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